adobe photoshop - How can I automatically find the opposite

I'd like to be able to automate the process of finding a color's opposite saturation or brightness level in Photoshop. (eg. opposite of 93% saturation is 7% saturation; opposite of 48% brightness i

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I have an image with very little banding in the sky, if put it on Photoshop and export it I get a lot more banding, I've tried all possible export settings but

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